Study on the synthesis of antibacterial plastic by using silver nanoparticles doped in zeolite framework
Main Article Content
Abstract
Silver nanoparticles (AgNPs) doped in the zeolite framework (AgNPs/Z) were successfully synthesized by γ-irradiation in ethanol solution of silver ion-zeolite (Ag+/Z) prepared by ion exchange reaction between silver nitrate (AgNO3) and zeolite 4A. The effects of the Ag+ concentration and irradiation dose on the formation of AgNPs/Z were also investigated. AgNPs/Z with the silver content of about 10,000 ppm and the average particle size of AgNPs of about 27 nm was characterized by ultraviolet-visible spectroscopy, powder X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM). Firstly, AgNPs/Z was added into PP resins for creation of PP-AgNPs/Z masterbatch (Ag content of ~10.000 ppm) and then PP-AgNPs/Z plastics were preapared by mixing masterbatch with PP resins. The antibacterial activity of the PP-AgNPs/Z plastics was investigated against Gram-negative bacteria Escherichia coli (E. coli). The results showed that PP-AgNPs/Z plastic contained 100 ppm of Ag possessed a high antibacterial property, namely the bactericidal effect was more than 96 % on the platic surface. In conclusion, possessing many advantages such as: vigorously antibacterial effect and good dispersion in plastic matrix, AgNPs/Z is promising to be applied as bactericidal agent for plastic industry.
Article Details
Keywords
Zeolite, silver nanoparticles, ion exchange, γ-irradiation, antibacterial plastic
References
[2]. J. Markarian, "Antimicrobial plastics additives: trends and latest developments in North America", Plastics Additives & Compounding, 4 (12):18-21, 2002.
[3]. JY. Kim et al., "Synthesis of silver nanoparticles within intercalated clay/polymer nanocomposite via in situ electron transfer reaction", Journal of Industrial and Engineering Chemistry, 17 (2):248-253, 2011.
[4]. K. Shameli et al., "Synthesis of silver/montmorillonite nanocomposites using γ-irradiation", International Journal of Nanomedicine, 5:1067-1077, 2010.
[5]. NTK. Lan et al., "Synthesis of silver nanoparticles deposited on silica by irradiation and preparation of PE/Ag nano compound masterbatchs", Advances In Natural Sciences: Nanoscience And Nanotechnology, 4, 045004, 2013.
[6]. K. Shameli et al., “Fabrication of silver nanoparticles doped in the zeolite framework and antibacterial activity”, International Journal of Nanomedicine, 6:331-341, 2011¬¬.
[7]. LV. Yaohui et al., “Silver nanoparticle-decorated porous ceramic composite for water treatment”, Journal of Membrane Science, 331:50-56, 2009.
[8]. JJ. Wu et al., "The synthesis of nano-silver/polypropylene plastics for antibacterial application", Current Applied Physics, 12:89-95, 2012.
[9]. F. Zhang et al., “Application of silver nanoparticles to cotton fabric as an antibacterial textile finish”, Fibers and Polymers, 10 (4):496-501, 2009.
[10]. DV. Phu et al., “Study of incorporation of silver nanoparticles onto PE-g-PAAc nonwoven fabric by -irradiation for water treatment”, Radiation Physics and Chemistry, 88:90-94, 2013.
[11]. SP. Ramnani et al., “Synthesis of silver nanoparticles supported on silica aerogel using gamma radiolysis”, Radiation Physics and Chemistry, 76:1290-1294, 2007.
[12]. D. Jiraroj et al., "Silver ions and silver nanoparticles in zeolite A composites for antibacterial activity", Powder Technology, 264:418-422, 2014.
[13]. L. Jiang et al., "Controllable embedding of silver nanoparticles on silica nanospheres using poly(acrylic acid) as a soft template", Nanotechnology, 18, 185603, 2007.
[14]. D. Klemečič et al., “Biodegradation of silver functionalised cellulose fibres”, Carbohydrate Polymers, 80 (2):426-435, 2010.
[15]. BD. Gussem et al., “Biogenic Silver for Disinfection of Water Contaminated with Viruses”, Applied and Environmental Microbiology, 76:1082-1087, 2010.
[16]. DT. Suyen, "Study on the fabrication of PP/Ag+/Zeolite compound for antibacterial PP composite by exchanging silver ion into zeolite framework", MSci thesis in Ho Chi Minh City University of Technology- Vietnam National University, 2013.